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Magnetic refrigeration is a relatively novel technology that has the potential to overcome some of the drawbacks of current vapor-compression cycles. Indeed, 17% of the worldwide electricity consumption is dedicated to refrigerator machines (Coulomb et al. 2015). This means that a relatively small improvement of the refrigeration technologies has a big impact on the global energy consumption. The main potential advantages of magnetic refrigeration are:

1. The use of a solid refrigerant which avoids spilling pollutants to the environment, like the halocarbon fluids of vapor-compressor machines. These chlorine containing

gases have been identified as the direct cause of the ozone depletion observed in earth's atmosphere. Furthermore, 20% of the global-warming produced by refrigerator machines is associated to the use of fluorocarbons (Coulomb et al. 2015).


2. The reduced noise during the operation of the refrigerator machine, due to the absence of compression and expansion stages.


3. The potential of an increased efficiency. This could come from the more isentropic phase change of the solid refrigerant, and the absence of inefficient processes like the compression and expansion stages of a vapor-compressor machines.


The first practical use of magnetic refrigeration was related to hydrogen liquefaction in the mid-70s (see Gschneidner and Pecharsky 2008). Then, research extended to refrigerators that worked at room temperature. In the mid-90s the US department of Energy funded an AMR laboratory to extend the knowledge to industrial room temperature refrigeration. Some of the publications yielded by that project boosted the research on magnetocaloric room temperature refrigerators. Among those are the discovery of a "giant" Magneto Caloric Effect (MCE) by Pecharsky and Gschneidner 1997, and a prototype that ran for 5000h over an 18 month period (Zimm et al. 1998). Since then, prototypes with increasingly higher cooling power and efficiency have been reported. Yu et al. 2010 reviewed many of the prototypes developed in the last decade. In their review a clear tendency towards the use of permanent magnets and rotatory prototypes was shown. Despite the recent developments, magnetic refrigeration still needs to face some challenges before becoming commercially viable**:

**as of 2019


1. Price of the raw materials to produce these refrigerators is still elevated**. This is because of the relatively high amount of rare earths the prototypes have (i.e. kilograms of Gadolinium (Gd), Neodymium (Nd)).

2. The physical phase transition of the solid refrigerant needs of a relatively strong magnetic field (around 1-2T). This is usually costly to produce, so the magnetized airgap tends to be relatively small (in the 10s of mm).


3. During the regular operation of a magnetic regenerator, multiple physical phenomena coexist in a porous medium. Fluid flow, heat transfer, and magnetic field dene the performance of the machine and are difficult to measure without being intrusive. Some efforts have been made to lower the cost of raw materials by searching for more earth abundant Magneto Caloric Materials (MCMs, see Tan et al. 2013). Other scientists have work optimizing the design of the necessary permanent magnet (Teyber et al. 2017). Also, some results have been published on the inner temperature measurement of Active Magnetic Regenerators*.

*Christiaanse et al., Measurement of adiabatic temperature change in a porous regenerator  using fibre bragg grating , volume 2, pages 315318. Canadian Congress of Applied Mechanics, Victoria, British Columbia, Canada, May 29-June 1, 2017).


The central piece of magnetic refrigeration is the magnetic phase change MCMs undergo in the vicinity of their Curie temperature (Tc). Similar to the latent heat of a fluid, the solid refrigerant suddenly experiences an atomic structural change, which modifies the entropy balance of the MCM. The total entropy of a MCM is often expressed by the following equation:



 

Screenshot 2019-04-02 17_28_33.png

By trying to approach a Brayton cycle the convective heat transfer can be as fast as possible, which increases the frequency at which the AMR can operate. This increases the cooling power, and makes up for the limited specific heat the MCM can pump.

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So, by (de)magntetizing externally the samples magnetic is modified and the temperature of the sample changes (if the environment is adiabatic). Some simplified mathematical models have been developed to calculate the entropy change (see Smart 1966). However, due to the introduced hypotheses not all MCMs follow the results predicted by the most popular model (Mean Field Theory). Generally, the specific entropy change of the available MCMs is relatively low. Thus, to attain a practical temperature span between the cold source and hot sink, several MCM cycles are linked one after the other. Because all cycles need to be magnetized, and the production of a high magnetic field is costly, the ensemble of cycles is compressed in a regenerator. In a more regeneral term, a regenerator is an intermediary device that connects thermodynamic cycles. In this specific case the regenerator is made of MCM, a solid substance that exerts thermodynamic work into the cycle. Therefore, the device is called an Active Magnetic Regenerator (AMR). The volume of the regenerator is filled of two phases: a solid MCM that is stationary, and the Heat Transfer Flow (HTF). So in an steady state operation the HTF surges from the cold source to the hot sink linking thermodynamically all the intermediate cycles. The cycles are usually conceptualized macroscopically in a continuous way along the full temperature span of the regenerator. So, the microscopic geometry of the regenerator defines how the applied magnetic field funnels into the MCM, how the heat is transferred by convection in and out the MCM, and what are the viscous losses of the fluid flow. The published prototypes to this date try to mimic a Brayton cycle for each of the differential points along the temperature span of the AMR:

 


1. Fast (quasi)adiabatic magnetization
2. HTF surge towards the hot sink
3. Fast (quasi)adiabatic demagnetization
4. HTF surge towards the cold source

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